The resulting compounds are called ionic compounds. Because opposite charges attract (while like charges repel), these oppositely charged ions attract each other, forming ionic bonds. Those that lose electrons become positively charged, and those that gain electrons become negatively charged. Because some atoms will lose electrons and some atoms will gain electrons, there is no overall change in the number of electrons, but with the transfer of electrons the individual atoms acquire a nonzero electric charge. One way is the transfer of electrons between two atoms until both atoms have octets. There are two ways for an atom that does not have an octet of valence electrons to obtain an octet in its outer shell. This useful rule of thumb is called the octet rule, and it is a key to understanding why compounds form. Chemists have concluded that atoms are especially stable if they have eight electrons in their outermost shell. What else do the noble gas elements have in common? Except for helium, they all have eight valence electrons. These elements-helium, neon, argon, krypton, xenon, and radon-do not form compounds very easily, which suggests that they are especially stable as lone atoms. What causes atoms to make a chemical bond with other atoms, rather than remaining as individual atoms? A clue comes by considering the noble gas elements, the rightmost column of the periodic table. Chemical bonds are formed when electrons in different atoms interact with each other to make an arrangement that is more stable than when the atoms are apart. 3.1 Two Types of BondingĪtoms can join together by forming a chemical bond, which is a very strong attraction between two atoms. We will see additional examples of such differences in section 3.3 of this chapter covering “Covalent Bonding and Simple Molecular Compounds”, as we consider how atoms combine to form compounds. Nevertheless, the compound has properties completely different from either elemental sodium (a chemically reactive metal) or elemental chlorine (a poisonous, green gas). Table salt, as we have seen, consists of only two elements: sodium and chlorine. Compounds can be very complex combinations of atoms, but many important compounds are fairly simple. There are only 118 known chemical elements but tens of millions of known chemical compounds. 3 Covalent Bonding and Simple Molecular Compounds Covalent Bonds Electron Sharing Covalent Bonds Between Different Atoms Multiple Covalent Bonds 3.4 Chapter Summary Ionic Compounds Covalent Compounds 3. 2 Ions Electron Transfer Lewis Diagrams 3. This text is published under creative commons licensing, for referencing and adaptation, please click here. For the interactive PDF, adobe reader is required for full functionality. It's thought that another one of these magic numbers lies just beyond the range of currently known elements, which means we could potentially discover some new elements that are relatively stable and extremely massive.This content can also be downloaded as a PDF file. There are believed to be certain numbers/ratios that are inherently more stable. Hence, larger atoms become more unstable. The ratio of neutrons to protons gradually increases to try to compensate, but this results in the neutrons getting more unstable themselves, resulting in more opportunity for weak forces to destabilize them. With all of that to consider, as you get larger and larger nuclei with more protons, the electromagnetic forces increase, as well as the distances in the nuclei, putting more strain on the nuclear forces holding it all together. Neutrons will help add to this nuclear force, but they tend to become unstable when they get into too great of concentration and the weak force will cause them to decay into protons. Fusion allows these protons to get close enough together for the stronger, yet short ranged, nuclear force to overpower the electromagnetic force. The electromagnetic force of the protons wants to push them away from each other. There are several forces at work inside the nuclei of atoms.
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That means you’re unlikely to get the full 10 years we used to get by moving Office to new PCs, and perhaps explains Microsoft’s attempts to reduce its 10-year support lifecycle. If you lose the activation code, you can’t get a new one without giving Microsoft proof of purchase.Ĭheaper versions of Office are locked to the PC on which they were originally installed. If you lose the DVDs, you can download the software. Boxed copies have more or less disappeared, but if you own one, you need to keep the code marked on the box to reinstall it. The traditional advantages of buying boxed copies of Office were that you could use it on two PCs (a desktop and a laptop, but not at the same time) and that you could transfer it to a new PC. But even if you switch to a free alternative, you’ll spend time learning a new interface and handling your old documents. If you are not a business, you can certainly live without it or use the free online version. If you’re paying staff, say, £20,000 to £60,000 a year, and can’t afford £100 a year for Office 365 – less for a boxed version – then you have bigger problems.ĭecide where you are on the spectrum from “I like it” to “can’t live without it”. This isn’t going to change in a hurry because Microsoft Office is also a platform with hundreds of add-ons and plug-ins, it’s supported by thousands of books, video tutorials, websites and consultants, and it’s what most office workers already know how to use.Īnd when time is money, the cost of sorting out incompatibilities and usability issues is far higher than the cost of Office. This applies in spades to files that use VBA (Visual Basic for Applications) and macros, and to Excel spreadsheets where errors can have career-ending financial consequences. The third reason is that we live in a world where Microsoft Office is the de facto standard for business documents, and you absolutely have to be able to read them accurately. But I found I still needed Word to compare files, and to cope with the publishing industry’s use of styles, comments and “ track changes”. Being text based, it’s hopeless for storing images, but it’s perfect for texts with simple formatting. rtf (rich text) file format, which almost any word processor can read. I tried to avoid this problem by saving all my files in Microsoft’s. But if your documents are simple text files, then a lot of programs will load them. If your documents include multiple columns, embedded images, custom fonts, footnotes and similar features, you can more or less forget about using anything else. This depends on the complexity of your files. The second reason is that you need it to read old files, which is one of your problems. That’s why I’ve used it for a couple of decades. The best is that you like using it, because of its power, rich feature list, ease of use or whatever. Word is powerful and flexible, but you pay for that utility. The main difference is that Microsoft’s programs are better, except for multiuser simultaneous editing. This is exactly the same as Google’s online suite. All you have to do is create a Microsoft Account using any working email address – it doesn’t have to be a Microsoft email address – and you can use online versions of Word, Excel and PowerPoint with free online storage in OneDrive. In fact, you can already use some Microsoft Office programs online, including Word, without paying Microsoft a penny. Microsoft would prefer both Mac and Windows users of Office to move to the online version, Office 365, but it’s still entirely up to you. Is there is a cheaper way of carrying on with Word, or, failing that, an alternative word processor with which I’ll still be able to open and edit my existing Word documents? Ed As a writer, I have a very large number of Word files, but with Microsoft moving to an annual subscription model, the cost of remaining with Word is looking prohibitive. I chose Microsoft Word for Mac when I switched to a MacBook Pro some years ago. However, without a clear understanding of key performance indicators (KPIs) and metrics, it can be difficult to make informed decisions about cash management.This is where a well-designed KPI dashboard comes into play. Leveraging Five Key Metrics to Enhance Cash Flow Forecasting and Financial Decision-Makingįor multinational corporations worldwide, effective cash flow forecasting is critical for financial success. Audit trail and compliance reporting to ensure regulatory compliance and accountability.Workflow automation to reduce the time and effort required to perform routine financial tasks.Elimination of time-consuming, error-prone, and manual cash flow processes to streamline your financial management.Automated notifications for critical financial metrics such as cash balance, liquidity ratio, and working capital.Real-time updates and alerts to provide quicker and more accurate decision-making.API integration with other financial management tools to streamline processes and improve efficiency.Automated data refresh and synchronization to ensure data accuracy and consistency.Integration with multiple internal and external data sources to provide a comprehensive view of your organization’s performance.Predictive analytics to anticipate future trends and risks.Pattern recognition to identify trends and opportunities for improvement.Automated anomaly detection to identify potential issues before they arise.Scenario modeling and stress-testing capabilities to assess the impact of potential changes in the business environment.Interactive cash flow optimization dashboards that provide real-time feeds and reports to support decision-making.Flexible, self-service dashboards that allow users to derive key business insights and create intuitive visualizations.DIY Functionality for Cash Flow Forecasting:.User-defined alerts and notifications to provide real-time updates on critical financial metrics.Data slicing and dicing with custom user-defined measures and calculated fields for a more granular view of financial performance.Multiple charting options for visualizing data in different ways.Integration of financial and non-financial data to provide a holistic view of your organization’s performance.Predictive modeling and forecasting capabilities to anticipate future trends and risks.Data mining with advanced analytics powered by artificial intelligence to extract key insights and trends.It provides an instant view of any cash flow hurdles that may be coming up, or where you may have excess cash in the business to distribute or invest. As you add reminder notices for overdue invoices or send automated emails another feature of cash manager (see Debt Management), the 30 day forecast will update automatically with revised dates that invoices are to be due. As you progress through the year, you can also generate new forecasts taking into account actual results to date and joining them to budget figures for the rest of the year.ģ0 Day Forecast takes your current customer and supplier invoices, Sales & Purchase orders (optional) and your Payroll, GST and PAYG commitments and use this information to predict your cash balance out for the next 30 days. From any of those budgets you can create a cash flow forecast with the click of a button, taking into account average day delays in receiving & making payments. Budgets can be modified quickly by percentage at a number of levels. There are 2 type of forecasts provided, a 12 month forecast from budget & actuals at a general ledger account level, and a 30 day forecast based on your outstanding customer and supplier invoices, Sales & Purchase orders (if desired) and your Payroll, GST and PAYG commitments.ġ2 month budget forecasts can take your business system budget and allow you to create as many variations of this as required. Up to date cash flow forecasting live from your business systemĬash Manager integrates directly into your business system to provide real time cash flow forecasting information. Humankind is remembered only in myth and legend. Their future is uncertain, although Grace Armstrong speaks in favor of allowing them to join Prosperity.PLEASE NOTE: You will need a free key to play our Alpha Demo that you can get for free on our website! In the distant future, the dawn of an intelligent machine civilization is taking place in a remote star system. With their leader gone, their home destroyed, and most of their brothers and sisters dead, the remaining New Edeners continue to roam Hope County attacking the Highwaymen. If left alive, Joseph disappears with the burnt body of his son. Joseph burns down his mystical apple tree and urges the Captain to kill him as he claims his soul is also corrupt - the player can either shoot and kill him, or spare him and leave him. The Captain is forced to put Ethan down, causing Joseph to fall into despair. Despite Joseph's protest and warning, Ethan takes a bite and is corrupted by it. After the Captain defeats the Twins, they and Joseph discover that Ethan is about to eat a sacred fruit from the sacred tree. Later in the game however, Ethan Seed betrays them to Mickey and Lou, and they attack and burn New Eden down, killing a large amount of the inhabitants. Joseph rallied New Eden to fight at the Captain's side in the war against the Highwaymen. The Captain returned however, empowered by their sacred fruit and with a living Joseph Seed, who hailed the Captain as New Eden's "shepherd" and "God's sword". In exchange for accomplishing Ethan's task, Ethan promised New Eden's support once the New Edeners saw Joseph was just a man and accepted him as the new prophet of New Eden. Ethan believes his father Joseph to be dead and tasked the Captain to find proof of Joseph's death. Ethan grows upset that the Captain retrieved Joseph's Word since they are now prophesied to lead New Eden. The Captain recovers Joseph's Word which allows them entrance into the New Eden compound and delivers the book to Ethan. The Security Captain is tasked by Kim Rye to ask for help from New Eden to take down the Highwaymen, although she makes it clear she's only doing it because she sees no better option. Joseph left New Eden in self-imposed exile to await this "shepherd" who would seek him out, leaving his prideful son, Ethan Seed, the de facto leader of New Eden. One day Joseph Seed dreamt of a "shepherd" that would realize the paradise he prophesied. Eventually, the New Edeners thrived and built their own community where they reject everything from the old world and strive to live off the land in peace. This empowerment allowed Joseph's followers to survive the post-apocalyptic winters, famine, and pestilence. Joseph Seed empowers his "chosen" with miraculous apples from his mystical tree which grants them superhuman strength and durability. They also abhor technology and intentionally destroy it every chance they get as they see technology as the cause of the Collapse. They live a primeval lifestyle, wearing animal skins and utilizing primitive tools and weapons such as bows and arrows. They are at war with the Highwaymen, whom they consider "locusts in their garden", and wage a guerilla war against them. New Eden is an established religious group born from the survivors of Project at Eden's Gate and live in the north of post-apocalyptic Hope County. All the survivors left the bunker to follow Joseph to the North, to settle this New Eden. Years after the event, Joseph Seed appeared at the bunker to rally his following survivors, telling them of a new world built by God for them to live in. Starvation, disease, and a constant threat of flooding threatened the survivors. Due to the damage the bunker had sustained in the fighting between the Cult and the Resistance, it was a difficult place to live. According to notes, after the Collapse, the surviving Cultists took refuge in the remains of John Seed's bunker.
They should also be able to hold your accessories and decor with a little room to spare, ensuring an uncluttered aesthetic. The key to designing a living space that’s equally functional and unified is to choose coffee tables and side tables that complement each other and the surrounding furniture without overwhelming the space. Though smaller than traditional coffee tables, side tables function similarly – they offer a convenient surface for beverages, decorative objects, reading material, and more. Ultimately, the best coffee table for your home will provide a convenient surface for seated guests and family members – and it will coincide with your interior design scheme. Before you begin shopping, note the size of your space and how many seats – including sofas, armchairs, and side chairs – will surround the coffee table. Coffee tables are available in a range of styles and sizes. The collection of original Eames furniture on 1stDibs includes chairs, tables, case pieces and other items.Central to any living area, coffee tables ground seating arrangements and anchor the small things that breathe life into a space: drinkware and coasters, house plants, decorative objects, candles, and more. In 1956 the Eames lounge chair and ottoman appeared - the supremely comfortable plywood-base-and-leather-upholstery creation that will likely live in homes as long as there are people with good taste and sense.Ĭharles Eames once said, “The role of the designer is that of a very good, thoughtful host anticipating the needs of his guests.” For very good collectors and thoughtful interior designers, a piece of design by the Eameses, the closer produced to original conception the better, is almost de rigueur - for its beauty and comfort, and not least as a tribute to the creative legacy and enduring influence of Charles and Ray Eames. The populist notion of “good design for all” drove their molded fiberglass chair series that same decade, and also produced the organic-form, ever-delightful La Chaise. Their Wire chair group of the 1950s, for example, was inspired by basket weaving techniques. The Eameses eagerly embraced new technology and materials, and one of their peculiar talents was to imbue their supremely modern design with references to folk traditions. Some of the first Eames items to emerge from Herman Miller are now classics: the LCW, or Lounge Chair Wood, and the DCM, or Dining Chair Metal, supported by tubular steel. The Navy contract allowed Charles to open a professional studio, and the attention-grabbing plywood furniture the firm produced prompted George Nelson, the director of design of the furniture-maker Herman Miller Inc., to enlist Charles and (by association, if not by contract) Ray in 1946. Navy for lightweight plywood leg splints for wounded servicemen - they are coveted collectibles today more so those that Ray used to make sculptures. The next year, they won a contract from the U.S. In the evenings at their apartment, they experimented with molded plywood using a handmade heat-and-pressurization device they called the “Kazam!” machine. They moved to Los Angeles in 1941, where Charles worked on set design for MGM. His technical skills and her artistic flair were wonderfully complementary. They met in 1940 at the Cranbrook Academy of Art in suburban Detroit (the legendary institution where Charles also met his frequent collaborator Eero Saarinen and the artist and designer Harry Bertoia) and married the next year. Ray (née Beatrice Alexandra Kaiser, 1912–88) was an artist, who studied under the Abstract Expressionist painter Hans Hofmann. They are the happy, ever-curious, ever-adventurous faces of modernism.Ĭharles (1907–78) studied architecture and industrial design. Charles Eames and Ray Eames were the embodiment of the inventiveness, energy and optimism at the heart of mid-century modern American design, and have been recognized as the most influential designers of the 20th century.Īs furniture designers, filmmakers, artists, textile and graphic designers and even toy and puzzle makers, the Eameses were a visionary and effective force for the notion that design should be an agent of positive change. You can see a movie for just $3 at theatres across Toronto this weekend You can see movies for free at Tubi and for free with your (u/TPL_on_Reddit) card on both Hoopla and Kanopy. You can also chat with other users who are watching the same channel. #Livestation player tv alternative for free# The free version of LiveStation player offers a number of free channels to watch the good ones are already there, namely, BBC, Al Jazeera, NASA TV, ESPN Live, and oh MTV, Cartoon Network and few other entertainment channels thrown in, in case you get bored watching the news. Join the first social network for virtual TV channels.Have a great night my Reddit GenX friend!! - Source: Reddit / about 1 month ago Who else can’t deal with dark, heavy themes in their entertainment anymore? I did the same with the Switch. I am looking for something where I can watch movies for free, similar to 9anime.to but for movies rather than anime Try Tubi, Plex, Kanopy, or Hoopla. VeohTV Player is a popular, free Mac software, that belongs to the category Audio & Video with. Please keep in mind that this app works only if you have a valid IPTV subscription.You may have better answers on a different subreddit though. Years after being teased fiveman is finally getting released by shout Most of the shout factory stuff is on tubi anyways. Many customers see LifeStation as a quality alternative to traditional Life Alert systems seen on TV commercials. This app is an android friendly alternative to MAG250 and other setup boxes that you have been using to stream IPTV channels. For more information, check out this comparison review with Life Alert. More than 30 alternatives to choose: FreeZ Online TV, Kite Player. LifeStation has plans to include an additional service that will allow their subscribers to book Uber rides by phone to and from their medical appointments. Livestation brings together one of the most impressive and widest selection of.
Sam took part in the " Defender for a Day", in which Nighthawk was trying to recruit new members. When Falcon found out that the Red Skull manipulated him and was the one that gave him powers, he joined up with SHIELD. When Falcon helped Black Panther, T'Challa rewarded him by giving him a costume with wings capable of flight. Even his soon-to-be girlfriend, Leila would call the Falcon "a yellowback", not knowing he was really Sam Wilson. He worked hard to be a hero for the Harlem community, but a certain section of the African-American populace viewed him an an "Uncle Tom". Sam even took the identity and costume of Captain America. Major Story Arcs A Hero is Bornīack in America, Steve helped Sam become a superhero and they even teamed together on several occasions. He is comics first mainstream African American hero, with the Black Panther being comics first African hero. He was created by Stan Lee and Gene Colan. Sam Wilson made his first appearance in Captain America #117. Using the Cosmic Cube, Red Skull gave Sam his telepathic communication with Redwing and created his Snap persona, the Red Skull turned him into the ideal fighter to take on Captain America, but Cap was able to snap Sam out the Skull's control, and together they defeated the Red Skull. On his way to Rio de Janeiro, his plane crashed and he was later found by the Red Skull. Consumed by grief and "angry at the world" Sam became a respected community volunteer and social worker to try to better his community. Two years later, his mother is shot and killed by a mugger one block from their apartment. The next night, however, Sam's father is killed trying to break up a neighborhood fight. To his surprise, rather than put up a fight, they provide him with books on different religions and comparative theology. When he is 16, Wilson refuses to go to church, believing his deeply religious parents' faith could be wrong. In his teens, however, he encounters racism for the first time which leaves him frustrated, jaded, and disappointed. He takes up training pigeons, and has the largest pigeon coop in Harlem. Sam's childhood started out a happy one during which he finds he has a natural affinity for birds. Sam was his parents' youngest child with older sister named Sarah and older brother named Gideon. Samuel Thomas Wilson was born in Harlem, New York City to Darlene and Paul Wilson, a prominent minister. Make various products, trade with the city, and achieve goals. Harvest produce and used it to upgrade your farm for more profit. Farm Frenzy 3 for Mac allows you to build your own farm and raise a variety of livestock, from chickens and sheep to penguins. And cats will help you gather resources – from eggs to cakes. Farm Frenzy 3 for Mac - Raise animals on your very own farm. Dogs will protect your animals from bears. Pets can help you drive away predators and collect food. Farm Frenzy Collection Enjoy the farmhouse gems with this solid set of 12 Farm Frenzy titles Join Scarlett throughout all of her adventures in hundreds of farming challenges. Be sure to gather it immediately when ready! And in winter, animals need your care and warmth. If you succeed, your friends will elect you leader of the. In autumn, the wind carries away not only the leaves but also your harvest. Travel the world on a frenzy of farming fun in Farm Frenzy 3, the latest game in the hit series Travel the world on a frenzy of farming fun in Farm Frenzy 3 Visit 5 exotic locations and help local farmers get their farms up and running with all-new animals, upgrades, products and more. On a sunny day, the grass on the level disappears much faster and needs to be watered all the time! And when it rains, the grass grows without water. Set up a cozy barn for your animals, upgrade warehouses, and get daily bonuses.Īdvanced 3D graphics with dynamic changing of the time of day and lighting for a complete immersion in rural life.įorecasters report a sharp change in weather and even the season! You own a great ranch, but it needs to be cleaned up. As you race to meet your goals on each level, ravenous bears and other animals will try to foil your efforts.īut don't worry you'll have the tools you need to deal with each of these beastly brutes.įrom sunup to sundown, Farm Frenzy is crazy, captivating fun! Chill out with an all-new Farm Frenzy adventure Join Scarlett as she travels to the North Pole to check out a farm she purchased through a newspaper ad. You'll have to stay on your sun-kissed toes, though. Slip into a pair of overalls and give us your best "Yee-haw!".įrom feeding feisty animals to gathering fresh eggs to making delicious pastries, you'll turn a humble little homestead into a booming agribusiness. "Grow and make resources to trade with the city, care for animals andīuild your dream ranch in Alawar's famous Frenzy Farm with a modern twist!" The Goode Family as Margo/Trish/Save-Big Check-Out Girl/Clothing Store Manager/Ms.Back at the Barnyard as Vet (2 episodes).The War at Home as Jamie Mandelbaum (1 episode).A native of Spokane, Washington, Julia Sweeney attended the University of. Father of the Pride as Britney (1 episode) Julia Sweeney, Keynote Speaker, TED Speaker, Saturday Night Live Alum and.Sex and the City as Sister Anne Marie (1 episode).What's New, Scooby-Doo? as Aunt Meg (1 episode).According to Jim as Bobbi Coker (1 episode).Teamo Supermo as Crandall's Mom (4 episodes).Baby Blues as Wanda MacPherson/Maggie Wizowski/Various Characters (6 episodes). Suddenly Susan as Rachel Fishman (1 episode).4 Her father was an attorney and federal prosecutor, while her mother was a homemaker. Discover Julia Sweeneys Biography, Age, Height, Physical Stats, Dating/Affairs, Family and career updates. 3rd Rock from the Sun as Patty (1 episode) Early life Sweeney was born and raised in Spokane, Washington, the daughter of Robert Mark Sweeney and Jeraldine 'Jeri' Sweeney ( ne Ivers). Julia Sweeney (Julia Anne Sweeney) was born on 10 October, 1959 in Spokane, Washington, U.S., is an American actress.Mr Show W Ith Bob And David as Vernice in 'Second Wind' (1 episode).Saturday Night Live as Various/Herself (1990-1994, 78 episodes).Mad About You as French Professor (1 episode).Riders In The Sky as Tunga Tujunga (1 episode) Irish descent Cancer survivors Former Roman Catholics Living people Warner Records artists Actresses from Spokane, Washington Actresses of Irish descent.Hard Time on Planet Earth as Gladys (1 episode).
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